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These are known as the van ~ a a r "equations When xl = 0, In ylo0 = Ai2; when x2 = 0, 1n y F = Abl The RedlichIKister expansion, the Margules equations, and the van Laar equations are all special cases of a general treatment based on rational functions, ie, on equations for GE/x1x2RT given by ratios of polynomials11 They provide great flexibility in the fitting of VLE data for binary systems However, they have scant theoretical foundation, and therefore fail to admit a rational basis for extension to multicomponent systems Moreover, they do not incorporate an explicit temperature dependence for the parameters, though this can be supplied on an ad hoc basis

Description The first argument specifies the maximum number of connections per second this service is allowed to handle If the rate exceeds this value, the service is temporarily disabled for the second argument number of seconds For example: cps = 50 10 This will disable a service for 10 seconds if the connection rate ever exceeds 50 connections per second

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Theoretical developments in the molecular thermodynamics of liquid-solution behavior are often based on the concept of local composition Within a liquid solution, local compositions, different from the overall mixture composition, are presumed to account for the short-range order and nonrandom molecular orientations that result from differences in molecular size and intermolecular forces The concept was introduced by G M Wilson in 1964 with the publication of a model of solution behavior since known as the Wilson equation12 The success of this equation in the correlation of VLE data prompted the development of alternative localcomposition models, most notably the NRTL (Non-Random-Two-Liquid) equation of Renon and prausnitz13 and the UNIQUAC (UNIversal QUAsi-Chemical) equation of Abrams and prausnitz14 A further significant development, based on the UNIQUAC equation, is the UNIFAC method,I5 in which activity coefficients are calculated from contributions of the various groups making up the molecules of a solution

Table 8-3 xinetd Configuration File Variables (cont)

'O~ohannesJacobus van Laar (1860-1938), Dutch physical chemist "H C Van Ness and M M Abbott, Classical Thermodynamics of Norzelectrolyte Solutions: With Applications to Phase Equilibria, Sec 5-7, McGraw-Hill, New York, 1982 1 2 ~ M Wilson, J Am Chem Soc, vol 86, pp 127-130, 1964 1 3 ~Renon and J M Prausnitz, AIChE J, vol 14, p 135-144, 1968 1 4 ~S Abrams and J M Prausnitz,AIChE J, vol 21, p 116-128, 1975 "UNIQUAC Functional-group Activity Coefficients; proposed by Aa Fredenslund, R L Jones, and J M Prausnitz, AIChE J,vol 21, p 1086-1099, 1975; given detailed treatment in the monograph: Aa Fredenslund, J Gmehling, and P Rasmussen, Vapor-Liquid Equilibrium using UNIFAC, Elsevier, Amsterdam, 1977

Using the finger service as an example, let s take a look at one of the simplest entries possible with xinetd:

The Wilson equation, like the Margules and van Laar equations, contains just two parameters for a binary system (Al2 and A21), and is written:

# default: on # description: The finger server answers finger requests Finger is \ # a protocol that allows remote users to see information such as login name and # last login time for local users service finger { socket_type = stream wait = no user = nobody server = /usr/sbin/infingerd disable = yes }

Note that A12and Azl must always be positive numbers The NRTL equation, containing three parameters for a binary system, is:

As you can see, the entry is self-explanatory The service name is finger, and because of the socket_type, we know this is a TCP service The wait variable tells us that there can be multiple finger processes running concurrently The user variable tells us that nobody will be the process owner Finally, the name of the process being run is /usr/ sbin/infingerd

Gl2 = exp(-atl2)

If you want a secure system, chances are you will run with only a few services there are some people who don t even run xinetd at all! It takes just a few steps to enable or disable a service For example, to enable a service, you would first enable it in the xinetd configuration file (or inetdconf if you are using inetd instead), restart the xinetd service, and finally test things out to make sure you have the behavior you expect To disable a service is just the opposite procedure NOTE The service we will be exploring is the echo service This service is internal to xinetd; ie, it is not provided by any external daemon Let s step through this process 1 Use any plain-text editor to edit the file /etc/xinetdd/echo-stream and change the variable disable to no:

Gzl = e x p ( - a ~ ~ ~ )

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